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สมัครสมาชิก | ลืมรหัสผ่าน

ทังสเตนคาร์ไบด์

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ทังสเตนคาร์ไบด์
       ทังสเตนคาร์ไบด์ (อังกฤษ: tungsten carbide) มีสูตรเคมีคือ WC ในรูปพื้นฐานจะมีลักษณะเป็นผงสีเทาละเอียด มี 2 โครงสร้างคือแบบหกเหลี่ยม (α-WC) และแบบลูกบาศก์ (β-WC)
 
       ทังสเตนคาร์ไบด์เตรียมได้จากการทำปฏิกิริยาระหว่างทังสเตนกับคาร์บอนที่อุณหภูมิ 1400–2000 °C[3] หรือให้ความร้อนกับทังสเตนไตรออกไซด์และแกรไฟต์โดยตรงที่ 900 °C หรือในแก๊สไฮโดรเจนที่ 670 °C ตามด้วยการคาร์บิวไรเซชันในแก๊สอาร์กอนที่ 1000 °C[4] หรือใช้วิธีการเคลือบด้วยไอเคมี เช่น
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะคลอไรด์กับไฮโดรเจนและมีเทนที่อุณหภูมิ 670 °C (1,238 °F)
 WCl6 + H2 + CH4 WC + 6 HCl
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะฟลูออไรด์กับไฮโดรเจนและเมทานอลที่อุณหภูมิ 350 °C (662 °F)
                WF6 + 2 H2 + CH3OH → WC + 6 HF + H2O
       ทังสเตนคาร์ไบด์มีจุดหลอมเหลวที่ 2,870 °C (5,200 °F) และจุดเดือดที่ 6,000 °C (10,830 °F) มีความแข็งระดับ 9 ตามมาตราโมสและประมาณ 2600 ตามมาตราวิกเคอส์[5] ทังสเตนคาร์ไบด์มีความแข็งเกร็งมากกว่าเหล็กกล้าประมาณ 2 เท่า มีค่ามอดุลัสของยังประมาณ 530–700 GPa (77,000–102,000 ksi)[2][6][5][7] โมดูลัสของแรงบีบอัด 630–655 GPa และโมดูลัสของแรงเฉือน 274 GPa[8]
 
ด้วยคุณสมบัติความแข็งและทนความร้อนสูง ทังสเตนคาร์ไบด์จึงใช้ทำเป็นเครื่องมือตัดหรือหัวเจาะ ใช้ทำกระสุนเจาะเกราะ เครื่องมือผ่าตัด อุปกรณ์กีฬา เครื่องประดับและอื่น ๆ
 
 
 
 
 
 
 
 
 
 
อ้างอิง
 
  1. Kurlov, p. 22
  2. Blau, Peter J. (2003). Wear of Materials. Elsevier. p. 1345. ISBN 978-0-08-044301-0.
  3. Pierson, Hugh O. (1992). Handbook of Chemical Vapor Deposition (CVD): Principles, Technology, and Applications. William Andrew Inc. ISBN 0-8155-1300-3.
  4. Zhong, Y.; Shaw, L. (2011). 'A study on the synthesis of nanostructured WC–10 wt% Co particles from WO3 , Co3O4 , and graphite'. Journal of Materials Science 46 (19): 6323–6331. Bibcode:2011JMatS..46.6323Z. doi:10.1007/s10853-010-4937-y.
  5. Groover, Mikell P. (2010). Fundamentals of Modern Manufacturing: Materials, Processes, and Systems. John Wiley & Sons. p. 135. ISBN 978-0-470-46700-8.
  6. Kurlov, p. 3
  7. Cardarelli, François (2008). Materials Handbook: A Concise Desktop Reference. Springer Science & Business Media. pp. 640–. ISBN 978-1-84628-669-8.
  8. Kurlov, pp. 30, 135
  9. Sprince, NL.; Chamberlin, RI.; Hales, CA.; Weber, AL.; Kazemi, H. (1984). 'Respiratory disease in tungsten carbide production workers'. Chest 86 (4): 549–557. PMID 6434250. doi:10.1378/chest.86.4.549.
  10. 12th Report on Carcinogens'. National Toxicology Program. http://ntp.niehs.nih.gov/go/roc12. เรียกข้อมูลเมื่อ 2011-06-24.
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ssssaa [41.35.161.xxx] เมื่อ 8/11/2023 00:54
6992
อ้างอิง

ssssaa
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ssssaa [41.35.161.xxx] เมื่อ 8/11/2023 01:00
6993
อ้างอิง

alisha9595
Religion, sexual activity, and love are the three vital that is significant these are the excellent element the every person in the period of the maturity. The daring companions in Gurgaon and the really charming, fascinating, confident, happy are the actual gamers enjoying with the effective innings with the sport fans close to town.
 
alisha9595 [45.251.48.xxx] เมื่อ 8/11/2023 14:18
6994
อ้างอิง

vaishali949
Rest guaranteed I will be a reasonable yet lucky friend on your arm any place we may go. I am excellent, bona fide, articulate and engrossing; you essentially won't locate any preferable anyplace over me.  
 
vaishali949 [116.206.158.xxx] เมื่อ 8/11/2023 14:39
6995
อ้างอิง

oberoialisha949
I am just your optimal Jaipur Escort. Here you can inform me about your dream and we will finish that, we have female fever Model escort, housewife and Punjabi young ladies. I am extremely fastidious about my customers on the off chance that I like the individual while visit via telephone I absolutely love to meet him I like respectable talking benevolent ladies regarding refined men and men positively.
 
oberoialisha949 [116.206.158.xxx] เมื่อ 8/11/2023 14:41
6996
อ้างอิง

renzy9496
There is no space for boredom because loveable postures will never tire you. Fill the most stylish color in the life and choose best contrast for mature services in the bed with stunning girl. Dehradun escort is the comfort zone for those people who want to meet with girl without any complications. Here, people come and choose a female for their intercourse. It is not just like fertilization because our culture present it like an art that each muscular should enjoy in his life many times. 
 
renzy9496 [116.206.158.xxx] เมื่อ 8/11/2023 14:41
6997
อ้างอิง

purvii9496
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purvii9496 [116.206.158.xxx] เมื่อ 8/11/2023 14:42
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