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สมัครสมาชิก | ลืมรหัสผ่าน

ทังสเตนคาร์ไบด์

อ่าน 771017 | ตอบ 8487
ทังสเตนคาร์ไบด์
       ทังสเตนคาร์ไบด์ (อังกฤษ: tungsten carbide) มีสูตรเคมีคือ WC ในรูปพื้นฐานจะมีลักษณะเป็นผงสีเทาละเอียด มี 2 โครงสร้างคือแบบหกเหลี่ยม (α-WC) และแบบลูกบาศก์ (β-WC)
 
       ทังสเตนคาร์ไบด์เตรียมได้จากการทำปฏิกิริยาระหว่างทังสเตนกับคาร์บอนที่อุณหภูมิ 1400–2000 °C[3] หรือให้ความร้อนกับทังสเตนไตรออกไซด์และแกรไฟต์โดยตรงที่ 900 °C หรือในแก๊สไฮโดรเจนที่ 670 °C ตามด้วยการคาร์บิวไรเซชันในแก๊สอาร์กอนที่ 1000 °C[4] หรือใช้วิธีการเคลือบด้วยไอเคมี เช่น
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะคลอไรด์กับไฮโดรเจนและมีเทนที่อุณหภูมิ 670 °C (1,238 °F)
 WCl6 + H2 + CH4 WC + 6 HCl
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะฟลูออไรด์กับไฮโดรเจนและเมทานอลที่อุณหภูมิ 350 °C (662 °F)
                WF6 + 2 H2 + CH3OH → WC + 6 HF + H2O
       ทังสเตนคาร์ไบด์มีจุดหลอมเหลวที่ 2,870 °C (5,200 °F) และจุดเดือดที่ 6,000 °C (10,830 °F) มีความแข็งระดับ 9 ตามมาตราโมสและประมาณ 2600 ตามมาตราวิกเคอส์[5] ทังสเตนคาร์ไบด์มีความแข็งเกร็งมากกว่าเหล็กกล้าประมาณ 2 เท่า มีค่ามอดุลัสของยังประมาณ 530–700 GPa (77,000–102,000 ksi)[2][6][5][7] โมดูลัสของแรงบีบอัด 630–655 GPa และโมดูลัสของแรงเฉือน 274 GPa[8]
 
ด้วยคุณสมบัติความแข็งและทนความร้อนสูง ทังสเตนคาร์ไบด์จึงใช้ทำเป็นเครื่องมือตัดหรือหัวเจาะ ใช้ทำกระสุนเจาะเกราะ เครื่องมือผ่าตัด อุปกรณ์กีฬา เครื่องประดับและอื่น ๆ
 
 
 
 
 
 
 
 
 
 
อ้างอิง
 
  1. Kurlov, p. 22
  2. Blau, Peter J. (2003). Wear of Materials. Elsevier. p. 1345. ISBN 978-0-08-044301-0.
  3. Pierson, Hugh O. (1992). Handbook of Chemical Vapor Deposition (CVD): Principles, Technology, and Applications. William Andrew Inc. ISBN 0-8155-1300-3.
  4. Zhong, Y.; Shaw, L. (2011). 'A study on the synthesis of nanostructured WC–10 wt% Co particles from WO3 , Co3O4 , and graphite'. Journal of Materials Science 46 (19): 6323–6331. Bibcode:2011JMatS..46.6323Z. doi:10.1007/s10853-010-4937-y.
  5. Groover, Mikell P. (2010). Fundamentals of Modern Manufacturing: Materials, Processes, and Systems. John Wiley & Sons. p. 135. ISBN 978-0-470-46700-8.
  6. Kurlov, p. 3
  7. Cardarelli, François (2008). Materials Handbook: A Concise Desktop Reference. Springer Science & Business Media. pp. 640–. ISBN 978-1-84628-669-8.
  8. Kurlov, pp. 30, 135
  9. Sprince, NL.; Chamberlin, RI.; Hales, CA.; Weber, AL.; Kazemi, H. (1984). 'Respiratory disease in tungsten carbide production workers'. Chest 86 (4): 549–557. PMID 6434250. doi:10.1378/chest.86.4.549.
  10. 12th Report on Carcinogens'. National Toxicology Program. http://ntp.niehs.nih.gov/go/roc12. เรียกข้อมูลเมื่อ 2011-06-24.
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Lawrence
Cold meat products Sausage products are a variety of meat products that are subjected to a smoking and drying process. Pork, beef, poultry or a mixture of these meats are used for their production. There are many types of sausages, including sausages, ham cookers, oyster mushrooms or brawns. Sausage products have many culinary applications - they can be an addition to sandwiches, salads, and can also be served as an independent snack. Many countries have their own traditional meat products, such as Polish sausage, German Frankfurt sausage, Italian mortadella or Spanish chorizo. Meat products are a rich source of protein, as well as vitamins and minerals, such as iron and zinc. However, due to their high fat and salt content, they should be eaten in moderation. Sausage products are often used in the kitchen as an addition to sandwiches, salads, casseroles and main courses. 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Lawrence [109.172.108.xxx] เมื่อ 23/07/2023 03:26
5445
อ้างอิง

Sabine
A slot will be empty. Buttons might be positioned inside of the toolbar using a named slot. It needs to be used inside of a toolbar and can include several kinds of buttons, together with standard buttons, menu buttons, and back buttons. Across five reels it’s your goal to align as many of the win symbols as you may. The Fairy Queen herself is the slot game’s wild image, probably changing different symbols wanted to complete a winning mixture alongside a win line. One look into her crystal ball (the game’s scatter symbol, three of them award you ten free spins) and your future will probably be trying all sorts of splendid! The convention has been happening since 1948 and is a significant second within the aviation planning diary, permitting the worldwide airline group the chance to fulfill for quickfire optimisation of their planned schedules, while taking a look at new opportunities for route and community growth. It ensures airline schedules can be planned in accordance with the airport capacity that’s available, stopping unnecessary delays on the day and optimizing the environment friendly use of this heavily demanded infrastructure when fully implemented.
 
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Sabine [81.181.198.xxx] เมื่อ 23/07/2023 03:54
5446
อ้างอิง

Cecelia
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Cecelia [154.92.124.xxx] เมื่อ 23/07/2023 04:45
5447
อ้างอิง

Javier
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Javier [199.34.90.xxx] เมื่อ 23/07/2023 05:09
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