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ทังสเตนคาร์ไบด์
       ทังสเตนคาร์ไบด์ (อังกฤษ: tungsten carbide) มีสูตรเคมีคือ WC ในรูปพื้นฐานจะมีลักษณะเป็นผงสีเทาละเอียด มี 2 โครงสร้างคือแบบหกเหลี่ยม (α-WC) และแบบลูกบาศก์ (β-WC)
 
       ทังสเตนคาร์ไบด์เตรียมได้จากการทำปฏิกิริยาระหว่างทังสเตนกับคาร์บอนที่อุณหภูมิ 1400–2000 °C[3] หรือให้ความร้อนกับทังสเตนไตรออกไซด์และแกรไฟต์โดยตรงที่ 900 °C หรือในแก๊สไฮโดรเจนที่ 670 °C ตามด้วยการคาร์บิวไรเซชันในแก๊สอาร์กอนที่ 1000 °C[4] หรือใช้วิธีการเคลือบด้วยไอเคมี เช่น
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะคลอไรด์กับไฮโดรเจนและมีเทนที่อุณหภูมิ 670 °C (1,238 °F)
 WCl6 + H2 + CH4 → WC + 6 HCl
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะฟลูออไรด์กับไฮโดรเจนและเมทานอลที่อุณหภูมิ 350 °C (662 °F)
                WF6 + 2 H2 + CH3OH → WC + 6 HF + H2O
       ทังสเตนคาร์ไบด์มีจุดหลอมเหลวที่ 2,870 °C (5,200 °F) และจุดเดือดที่ 6,000 °C (10,830 °F) มีความแข็งระดับ 9 ตามมาตราโมสและประมาณ 2600 ตามมาตราวิกเคอส์[5] ทังสเตนคาร์ไบด์มีความแข็งเกร็งมากกว่าเหล็กกล้าประมาณ 2 เท่า มีค่ามอดุลัสของยังประมาณ 530–700 GPa (77,000–102,000 ksi)[2][6][5][7] โมดูลัสของแรงบีบอัด 630–655 GPa และโมดูลัสของแรงเฉือน 274 GPa[8]
 
ด้วยคุณสมบัติความแข็งและทนความร้อนสูง ทังสเตนคาร์ไบด์จึงใช้ทำเป็นเครื่องมือตัดหรือหัวเจาะ ใช้ทำกระสุนเจาะเกราะ เครื่องมือผ่าตัด อุปกรณ์กีฬา เครื่องประดับและอื่น ๆ
 
 
 
 
 
 
 
 
 
 
อ้างอิง
 
  1. Kurlov, p. 22
  2. Blau, Peter J. (2003). Wear of Materials. Elsevier. p. 1345. ISBN 978-0-08-044301-0.
  3. Pierson, Hugh O. (1992). Handbook of Chemical Vapor Deposition (CVD): Principles, Technology, and Applications. William Andrew Inc. ISBN 0-8155-1300-3.
  4. Zhong, Y.; Shaw, L. (2011). 'A study on the synthesis of nanostructured WC–10 wt% Co particles from WO3 , Co3O4 , and graphite'. Journal of Materials Science 46 (19): 6323–6331. Bibcode:2011JMatS..46.6323Z. doi:10.1007/s10853-010-4937-y.
  5. Groover, Mikell P. (2010). Fundamentals of Modern Manufacturing: Materials, Processes, and Systems. John Wiley & Sons. p. 135. ISBN 978-0-470-46700-8.
  6. Kurlov, p. 3
  7. Cardarelli, François (2008). Materials Handbook: A Concise Desktop Reference. Springer Science & Business Media. pp. 640–. ISBN 978-1-84628-669-8.
  8. Kurlov, pp. 30, 135
  9. Sprince, NL.; Chamberlin, RI.; Hales, CA.; Weber, AL.; Kazemi, H. (1984). 'Respiratory disease in tungsten carbide production workers'. Chest 86 (4): 549–557. PMID 6434250. doi:10.1378/chest.86.4.549.
  10. 12th Report on Carcinogens'. National Toxicology Program. http://ntp.niehs.nih.gov/go/roc12. เรียกข้อมูลเมื่อ 2011-06-24.
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Connectresources
Connect Resources is the UAE’s leading Recruitment and Staffing Agency in Dubai and an official alliance of Randstad. We offer supreme HR consultancy services and staffing solutions to our clients in the Middle East. We foster an unparalleled industry insight and a sophisticated consultative approach for both partners and job seekers to meet all your HR consultancy needs and solutions
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Connectresources [83.110.173.xxx] เมื่อ 16/10/2022 22:17
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Connectresources
Connect Resources is the UAE’s leading Recruitment and Staffing Agency in Dubai and an official alliance of Randstad. We offer supreme HR consultancy services and staffing solutions to our clients in the Middle East. We foster an unparalleled industry insight and a sophisticated consultative approach for both partners and job seekers to meet all your HR consultancy needs and solutions
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Connectresources [83.110.173.xxx] เมื่อ 16/10/2022 22:18
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